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Refinement of a microfurnace pyrolysis-GC–MS method for quantification of tire and road wear particles (TRWP) in sediment and solid matrices by Sharlee L. More; Julie V. Miller; Stephanie A. Thornton; Kathy Chan; Timothy R. Barber; Kenneth M. Unice is a Environmental Science article available to read on EtoBox.

What is Refinement of a microfurnace pyrolysis-GC–MS method for quantification of tire and road wear particles (TRWP) in sediment and solid matrices about?

Tire and road wear particles (TRWP) are produced by abrasion at the interface of the pavement and tread surface and contain tread rubber with road mineral encrustations. Quantitative thermoanalytical methods capable of estimating TRWP concentrations are needed to assess the prevalence and environmental fate of these particles. However, the presence of complex organic constituents in sediment and other environmental samples presents a challenge to the reliable determination of TRWP concentrations using current pyrolysis-gas chromatography–mass spectrometry (Py-GC–MS) methodologies. We are unaware of a published study evaluating pretreatment and other method refinements for microfurnace Py-GC–MS analysis of the elastomeric polymers in TRWP including polymer-specific deuterated internal standards as specified in ISO Technical Specification (ISO/TS) 20593:2017 and ISO/TS 21396:2017. Thus, potential method refinements were evaluated for microfurnace Py-GC–MS, including chromatography parameter modification, chemical pretreatment, and thermal desorption for cryogenically-milled tire tread (CMTT) samples in an artificial sediment matrix and a sediment field sample. The tire tread dimer ma

Who reads Refinement of a microfurnace pyrolysis-GC–MS method for quantification of tire and road wear particles (TRWP) in sediment and solid matrices?

It is typically read by researchers, students, and practitioners in Environmental Science.

Author
Sharlee L. More; Julie V. Miller; Stephanie A. Thornton; Kathy Chan; Timothy R. Barber; Kenneth M. Unice
Publisher
Elsevier BV
Published
2023
Language
EN
Field
Environmental Science (Physical Sciences)

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