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Chirality and Order in Binary Molecular Crystals of Inert Cobalt(III) ComplexesDedicated to Professor Joachim Strähle on the Occasion of his 65thBirthday by Ulli Englert; Axel Häring; Chunhua Hu; Irmgard Kalf is a Chemistry article available to read on EtoBox.

What is Chirality and Order in Binary Molecular Crystals of Inert Cobalt(III) ComplexesDedicated to Professor Joachim Strähle on the Occasion of his 65thBirthday about?

Starting from the enantiomerically pure and racemic chiral Lewis bases 1-phenylethylamine and 1-(1-naphthyl)ethylamine inert cobalt(III) complexes of the general composition Co(Hdmg) 2 (lig)X (Hdmg ϭ dimethylglyoximate; lig ϭ Lewis base; X ϭ CN, NCO, NO 2 ) were synthesized and characterized by single crystal X-ray diffraction. The enantiopure complexes were used as building blocks for the synthesis of binary crystals. Solid solutions resulted from cocrystallizing isomorphous compounds of equal chirality whereas complexes of opposite chirality formed well-ordered heterochiral solids with efficient packing. Two binary crystals of ## Chiralität und Ordnung in binären Molekülkristallen inerter Cobalt(III) Komplexe Inhaltsübersicht. Ausgehend von den enantiomerenreinen und racemischen chiralen Lewisbasen 1-Phenylethylamin and 1-(1-Naphthyl)ethylamin wurden inerte Cobalt(III)-Komplexe der allgemeinen Zusammensetzung Co(Hdmg) 2 (lig)X (Hdmg ϭ Dimethylglyoximat; lig ϭ Lewisbase; X ϭ CN, NCO, NO 2 ) synthetisiert und anhand von Einkristall-Strukturanalysen charakterisiert. Die enantiomerenreinen Komplexe wurden als Bausteine für die Herstellung binärer Kristalle eingesetzt. Isomorphe Verbi

Who reads Chirality and Order in Binary Molecular Crystals of Inert Cobalt(III) ComplexesDedicated to Professor Joachim Strähle on the Occasion of his 65thBirthday?

Author

Ulli Englert; Axel Häring; Chunhua Hu; Irmgard Kalf

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

2002

Language

EN

Field

Chemistry (Physical Sciences)