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Global phase behavior for CO2-philic solids: the CO2 + β-d-maltose octaacetate system by Lei Hong; Mark C. Thies; Robert M. Enick is a Engineering article available to read on EtoBox.

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High-pressure phase behavior for a binary mixture of the CO 2 -philic solid ␤-d-maltose octaacetate (MOA, T m = 432 K) with carbon dioxide was determined. Both critical end points (LCEP and UCEP) and pressure versus composition isotherms at 283, 298, and 323 K were measured in order to identify the global phase behavior for this system. Limited pressure-composition measurements were also made down to 253 K to determine whether liquid-liquid equilibria re-emerged at lower temperatures. The pressure-temperature projection of this system has the fluid-phase features of a Scott and Van Konynenburg Type V system. The solid-fluid behavior consists of a continuous, three-phase VL 2 S 2 curve that goes through a pressure maximum before running just below and parallel to the three-phase VL 1 L 2 line to lower pressures and temperatures. Another distinguishing feature of the CO 2 + MOA system is a long VL 1 L 2 line, which extends over a range of more than 20 K. The solubility of MOA in CO 2 can be explained by the interaction between a Lewis base (the carbonyl groups of MOA) and a Lewis acid (CO 2 ). The observed phase behavior, which is relatively rare, is likely to be observed for other h

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Author

Lei Hong; Mark C. Thies; Robert M. Enick

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0896-8446)

Published

2005

Language

EN

Field

Engineering (Physical Sciences)