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Synthesis of Nitrogen-Containing Heterocycles via Imidoyl or Iminyl Radical Intermediates by Jian Lei; Dengke Li; Qiang Zhu is a book available to read on EtoBox.

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This volume describes the recent developments in the free-radical mediated synthesis and elaboration of heterocycles. The first chapter, dealing with radical cascade processes illustrates the power and the beauty of radical chemistry with some striking examples of total synthesis of complex natural heterocycles. As organic chemists strive towards sustainability, radical chemistry has recently seen major advances and efforts in this direction, including C-H activation of arenes and unactivated alkyl groups. Photochemical activation, for a long time the preferred mode of activation in radical chemistry has also seen an unexpected revival with the advent of visible light metal- and organocatalyzed photoredox processes. A survey of these emerging areas is provided along with the concepts at the origin of these developments. The venerable Minisci reaction allows for direct access to functionalized heterocycles. This process has lately seen an interesting renaissance and is discussed in this volume. Addition of heteroatom-centered radicals onto unsaturated systems constitutes another powerful method to construct heterocycles. Examples of such a strategy are proposed along with the format

Author

Jian Lei; Dengke Li; Qiang Zhu

Publisher

Springer International Publishing : Imprint : Springer

Published

2017

Language

EN

ISBN

9783319895215

Subjects

Science, Chemistry, Stem