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Asymmetric construction of quaternary carbon stereocenter by Pd-hemilabile ligand-catalyzed allylic substitution by Yoshimasa Fukuda; Kazuhiro Kondo; Toyohiko Aoyama is a Chemistry article available to read on EtoBox.
What is Asymmetric construction of quaternary carbon stereocenter by Pd-hemilabile ligand-catalyzed allylic substitution about?
The catalyst comprised [PdCl(g 3 -C 3 H 5 )] 2 and a simple chiral hemilabile ferrocene ligand, 1 0 ,2-bis(diphenylphosphinoethyl)ferrocenyl alcohol, provides synthetically acceptable results for an enantioselective Pd-catalyzed allylic alkylation of cyclohexanone derivatives bearing an electron-withdrawing group at the a-position to form the quaternary carbon with up to 90% enantioselectivity under mild reaction conditions.
Who reads Asymmetric construction of quaternary carbon stereocenter by Pd-hemilabile ligand-catalyzed allylic substitution?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Yoshimasa Fukuda; Kazuhiro Kondo; Toyohiko Aoyama
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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