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What is Debye-Hückel Limiting Law Explained about?
The Debye-Huckel theory proposes that in concentrated solutions, activity coefficients deviate from unity due to inter-ionic forces between ions of strong electrolytes. The theory states that each ion has an ionic atmosphere of opposite charge surrounding it. Only in infinitely dilute solutions are these inter-ionic forces negligible, resulting in activity coefficients equal to unity. The Debye-Huckel theory provides an explanation for why activity coefficients differ from unity in concentrated solutions of
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- Photon Online Science Academy
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- EN