Skip to content

Opening book details…

Can I read Chemical reactions and phase equilibria of model halocarbons and salts in sub- and supercritical water (200–300 bar, 100–600°C) on EtoBox?

Chemical reactions and phase equilibria of model halocarbons and salts in sub- and supercritical water (200–300 bar, 100–600°C) by Jefferson W. Tester; Philip A. Marrone; Matthew M. DiPippo; Kentaro Sako; Matthew T. Reagan; Tomas Arias; William A. Peters is a Engineering article available to read on EtoBox.

What is Chemical reactions and phase equilibria of model halocarbons and salts in sub- and supercritical water (200–300 bar, 100–600°C) about?

Experimental data and theoretical predictions of hydrolysis reaction kinetics of model halocarbons and phase equilibria of their associated neutralized salt reaction products are reported for a range of hydrothermal conditions. Specifically, the results of a study of hydrolysis and oxidation of methylene chloride (CH 2 Cl 2 O, and HCl as final mineralized products are presented. An analysis of hydrolysis kinetics and heat transfer was used to generate kinetic parameters for comparison with theoretical predictions based on a modified form of the Kirkwood solution model to show density dependent effects as a function of the dielectric strength of the reaction solvent medium. Phase equilibria data for the ternary NaCl-Na 2 SO 4 -H 2 O, system at 200 and 250 bar were measured and correlated. A modified form of the Anderko-Pitzer semi-empirical PVTx i model was used to predict equilibrium phase boundaries for the NaCl-H 2 O system at 210, 250, and 300 bar. Molecular simulation results for the NaCl-H 2 O binary was used to illustrate changes in the solvation power of water as a function of density.

Who reads Chemical reactions and phase equilibria of model halocarbons and salts in sub- and supercritical water (200–300 bar, 100–600°C)?

It is typically read by researchers, students, and practitioners in Engineering.

Author
Jefferson W. Tester; Philip A. Marrone; Matthew M. DiPippo; Kentaro Sako; Matthew T. Reagan; Tomas Arias; William A. Peters
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0896-8446)
Published
1998
Language
EN
Field
Engineering (Physical Sciences)

More by Jefferson W. Tester; Philip A. Marrone; Matthew M. DiPippo; Kentaro Sako; Matthew T. Reagan; Tomas Arias; William A. Peters

Browse all works by Jefferson W. Tester; Philip A. Marrone; Matthew M. DiPippo; Kentaro Sako; Matthew T. Reagan; Tomas Arias; William A. Peters