Opening book details…
Can I read Über die Tricyanatomercurate KHg(NCO)~3~ und RbHg(NCO)~3~ — Synthesen, Kristallstrukturen und Schwingungsspektren on EtoBox?
Über die Tricyanatomercurate KHg(NCO)~3~ und RbHg(NCO)~3~ — Synthesen, Kristallstrukturen und Schwingungsspektren by Thiele, Gerhard; Hilfrich, Peter is a Chemistry article available to read on EtoBox.
What is Über die Tricyanatomercurate KHg(NCO)~3~ und RbHg(NCO)~3~ — Synthesen, Kristallstrukturen und Schwingungsspektren about?
By mixing aqueous solutions of Hg(CH3COO)2 and KOCN the white precipitate K2Hg3(NCO)8 is formed. When recrystallised from CH3OH colorless crystals of the compound KHg(NCO)3 are obtained. The crystal structure analysis (space group Pnma; α = 1015.2(6) pm, b = 399.3(3) pm, c = 1772.9(9) pm) shows a distorted KCdCl3 arrangement with isolated Hg(NCO)2 molecules, K+ and NCO- ions. The vibrational spectra in the range of 250-3000 cm-1 are discussed. The rubidium compound is isotypous (a = 1019.0(6) pm, b = 411.6(4) pm, c = 1820.5(8) pm).
Who reads Über die Tricyanatomercurate KHg(NCO)~3~ und RbHg(NCO)~3~ — Synthesen, Kristallstrukturen und Schwingungsspektren?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Thiele, Gerhard; Hilfrich, Peter
- Publisher
- Verlag der Zeitschrift fr Naturforschung; Walter de Gruyter GmbH (ISSN 0932-0776)
- Published
- 1977
- Language
- DE
- Field
- Chemistry (Physical Sciences)