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Organic‐inorganic Hybrid Lanthanide‐Silver Heterometallic Coordination Frameworks Constructed from Oxalate and Sulfate Anion: Syntheses, Structures, and Photoluminescent Properties by Xueying Xiao; Yongqin Wei; Wenxu Zheng; Prof. Dr. Kechen Wu is a Chemistry article available to read on EtoBox.

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## Abstract The first four examples of organic‐inorganic hybrid lanthanide‐silver heterometallic frameworks, namely, [Ag__Ln__(μ~5~‐C~2~O~4~)(SO~4~)(H~2~O)~2~] [__Ln__ = Eu (1) and Sm (2)] and [Ag__Ln__(μ~4~‐C~2~O~4~)~0.5~(μ~6~‐C~2~O~4~)~0.5~(SO~4~)(H~2~O)] [__Ln__ = Tb (3) and Dy (4)] based on oxalate and sulfate anions were synthesized by hydrothermal reactions of lanthanide oxide, silver nitrate, oxalic acid and sulfuric acid. All structures contain ladder‐like inorganic lanthanide sulfato chains, which are further connected together through silver atoms by oxalate anions with different coordination behavior (μ~5~‐C~2~O~4~: 1 and 2, μ~6~‐C~2~O~4~ mixed μ~4~‐C~2~O~4~: 3 and 4) to generate two types of 3D networks. The luminescent properties of these compounds were also studied.

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Author

Xueying Xiao; Yongqin Wei; Wenxu Zheng; Prof. Dr. Kechen Wu

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

2011

Language

EN

Field

Chemistry (Physical Sciences)