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^13^C NMR determination of the microstructure of polypropylene obtained with the DADNi(NCS)~2~/methylaluminoxane catalyst system by Griselda Barrera Galland; Luciana P. Da Silva; Marcos L. Dias; Geraldo L. Crossetti; Cláudio M. Ziglio; Carlos A. L. Filgueiras is a Materials Science article available to read on EtoBox.
What is ^13^C NMR determination of the microstructure of polypropylene obtained with the DADNi(NCS)~2~/methylaluminoxane catalyst system about?
## Abstract A complete ^13^C NMR characterization of a polymer synthesized with a new Ni‐diimine complex [DADNi(NCS)~2~, where DAD = __2,6__‐__iPr____C__~__6__~__H__~__3__~__N____C(Me)____C(Me)__ __N____2,6__‐__iPr____C__~__6__~__H__~__3__~] activated by methylaluminoxane by homopolymerization of propylene is presented. The amorphous material was made up mainly of blocks of syndiotactic polypropylene and ethylene–propylene copolymer. Some degree of propylene inversion (<1.2 mol %) and of long isobutyl and 2‐methyl hexyl branching (<1 mol %) were assigned and quantified. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2171–2178, 2004
Who reads ^13^C NMR determination of the microstructure of polypropylene obtained with the DADNi(NCS)~2~/methylaluminoxane catalyst system?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Griselda Barrera Galland; Luciana P. Da Silva; Marcos L. Dias; Geraldo L. Crossetti; Cláudio M. Ziglio; Carlos A. L. Filgueiras
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)
- Published
- 2004
- Language
- EN
- Field
- Materials Science (Physical Sciences)