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Can I read Impact of the R and Mg on the structural, hydrogenation and magnetic properties of R3-Mg Co9 (R = Pr, Nd, Tb and Y) compounds on EtoBox?
Impact of the R and Mg on the structural, hydrogenation and magnetic properties of R3-Mg Co9 (R = Pr, Nd, Tb and Y) compounds by Vitalii Shtender; Valérie Paul-Boncour; Roman Denys; Daniel Hedlund; Peter Svedlindh; Ihor Zavaliy is a Materials Science article available to read on EtoBox.
What is Impact of the R and Mg on the structural, hydrogenation and magnetic properties of R3-Mg Co9 (R = Pr, Nd, Tb and Y) compounds about?
R 2MgCo9 (R = Pr, Nd, Tb and Y) compounds have been synthesized by a powder sintering method and the corresponding hydrides have been prepared by a solid gas method. Their crystal structures and magnetic properties have been systematically studied. X-ray diffraction analysis showed that all R 2MgCo9 compounds belong to the PuNi3-type structure. The elements Tb, Y, Nd, Pr yield a lowering of the equilibrium pressure which correlates well with the increase in cell volume. The R 2MgCo9H(D) x (R = Pr, Nd, Tb and Y; (9.4 ≤ x ≤ 12)) hydrides (deuterides) preserve the PuNi3-type structure with hydrogenation-induced volume expansion ranging from 14.7 to 19.6%. The substitution of deuterium for hydrogen in R 2MgCo9–(H,D)2 (R = Tb and Y) prevents fast desorption at room temperature and ambient pressure. As for the magnetic properties, all the studied intermetallic compounds show ferromagnetic or ferrimagnetic behavior, and in some cases a temperature dependent spin reorientation. Hydrogen insertion reduces the magnetization and decreases the magnetic ordering temperature ( T C ), whereas Mg for R substitution increases T C .
Who reads Impact of the R and Mg on the structural, hydrogenation and magnetic properties of R3-Mg Co9 (R = Pr, Nd, Tb and Y) compounds?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Vitalii Shtender; Valérie Paul-Boncour; Roman Denys; Daniel Hedlund; Peter Svedlindh; Ihor Zavaliy
- Publisher
- Elsevier BV
- Published
- 2022
- Language
- EN
- Field
- Materials Science (Physical Sciences)