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ChemInform Abstract: Enantioselective Synthesis of β-Dibenzylamino Alcohols via a Dynamic Kinetic Resolution of α-Halo Acids. by J. A. O'MEARA; N. GARDEE; M. JUNG; R. N. BEN; T. DURST is a Chemistry article available to read on EtoBox.

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Enantioselective Synthesis of β-Dibenzylamino Alcohols via a Dynamic Kinetic Resolution of α-Halo Acids. -The title compounds (IV), precursors of synthetically important Reetz aldehydes, are prepared by highly diastereoselective amination of α-bromo esters (I). The high yields obtained in this amination are explained by a dynamic kinetic resolution process in which the (R,R) isomer of (I) reacts more quickly with the amine than the (S,R) isomer, and the released bromide or the added iodide serve to epimerize the slow reacting isomer. -(O'MEARA,

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Author

J. A. O'MEARA; N. GARDEE; M. JUNG; R. N. BEN; T. DURST

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley (ISSN 0931-7597)

Published

1998

Language

EN

Field

Chemistry (Physical Sciences)