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The document discusses an innovative iron-mediated segment coupling method for synthesizing ε-oxo alkene derivatives through C−C radical translocation and oxidative 1,5/6-hydrogen atom transfer (HAT). This approach allows for the rapid formation of various functionalized esters, ketones, sulfones, and phosphonates, with mechanistic insights provided by bond dissociation energy (BDE) analysis and control experiments. The study highlights the method

Author

aimiitdelhi202324

Language

EN