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This document summarizes a numerical model for calculating vapor-liquid-liquid equilibria (VLLE) in binary mixtures. The model uses only readily available parameters like vapor pressures of the pure components and does not require experimental data. Activity coefficients are determined using regular solution theory and excess Gibbs energy is determined using a two-constant Margules expression. Calculated results for nitrogen-ethane, nitrogen-ethylene, and nitrogen-propane mixtures agree well with experiment

Author

rahul

Language

EN