Can I read Bis[μ-1,2-bis(2-pyridyl)ethyne-κ2N:N′]bis[aquadinitratocadmium(II)] on EtoBox?

Bis[μ-1,2-bis(2-pyridyl)ethyne-κ2N:N′]bis[aquadinitratocadmium(II)] by Md. Badruz Zaman; Matthew J. Davis; Mark D. Smith; Hans-Conrad zur Loye is a Chemistry article available to read on EtoBox.

What is Bis[μ-1,2-bis(2-pyridyl)ethyne-κ2N:N′]bis[aquadinitratocadmium(II)] about?

Two twisted 1,2-bis(2-pyridyl)ethyne ligands bridge two Cd(2+) centers in the C(2)-symmetric title complex, [Cd(2)(NO(3))(4)(mu-C(12)H(8)N(2))(2)(H(2)O)(2)]. The bridging ligands arch across one another creating a 'zigzag loop' molecular geometry. Two nitrate ions and a water molecule complete the irregular seven-coordinate Cd-atom environment. The dihedral angles between the equivalent pyridyl ring planes of the two independent ligands are 67.2 (1) degrees. O(water)-H.O(nitrate) hydrogen bonding creates two-dimensional layers parallel to the ab plane.

Who reads Bis[μ-1,2-bis(2-pyridyl)ethyne-κ2N:N′]bis[aquadinitratocadmium(II)]?

Author

Md. Badruz Zaman; Matthew J. Davis; Mark D. Smith; Hans-Conrad zur Loye

Publisher

International Union of Crystallography; Blackwell Publishing Inc.; International Union of Crystallography (IUCr); Wiley (ISSN 0108-2701)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)