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Two New Crystalline Organogermanate‐Based Inorganic‐Organic Hybrid Compounds by Prof. Dr. Norbert Stock; Christian Jargstorff; Steffanie Wriedt is a Chemistry article available to read on EtoBox.

What is Two New Crystalline Organogermanate‐Based Inorganic‐Organic Hybrid Compounds about?

## Abstract The bifunctional metalloligand bis(carboxyethylgermanium)sesquioxide, (HOOCCH~2~CH~2~Ge)~2~O~3~, was employed in the systematic high‐throughput (HT) investigation of the system Zn^2+^/(HOOCCH~2~CH~2~Ge)~2~O~3~/H~2~O/C~4~H~9~OH. Two new metal‐organogermanates Zn[(OOCCH~2~CH~2~Ge)~2~O~3~] (1) and Zn~2~(O~3~GeCH~2~CH~2~COO) (2) were discovered that show two new structural motifs for this class of compounds. Whereas in compound 1 a formal intercalation in the structure of (HOOCCH~2~CH~2~Ge)~2~O~3~ is observed, 2 exhibits a new layered structure composed of CGeO~3~ and ZnO~4~ unit linked by μ~3~‐oxygen atoms. Both connectivity modes lead to dense three‐dimensional framework structures.

Who reads Two New Crystalline Organogermanate‐Based Inorganic‐Organic Hybrid Compounds?

Author

Prof. Dr. Norbert Stock; Christian Jargstorff; Steffanie Wriedt

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

2011

Language

EN

Field

Chemistry (Physical Sciences)