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Bismuth impregnated biochar for efficient uranium removal from solution: Adsorption behavior and interfacial mechanism 1 1. Introduction 1 2. Materials and methods 2 2.1. Reagents and chemicals 2 2.2. Synthesis of Bi2O3 doped horse manure-derived biochar 2 2.3. Characterization 2 2.4. Batch experiments 2 3. Results and discussion 3 3.1. Characterization 3 3.1.1. FT-IR 3 3.1.2. XRD 3 3.1.3. TG 4 3.1.4. XPS 4 3.1.5. SEM 5 3.2. Adsorption 5 3.2.1. Effect of pH and zeta potential 5 3.2.2. Effect of adsorbent dose 6 3.2.3. Effect of interfering ions and ionic strength 6 3.2.4. Effect of the doped Bi2O3 on the adsorption 7 3.2.5. Adsorption kinetics and isotherms 7 3.2.6. Mechanism 8 4. Conclusion 9 CRediT authorship contribution statement 10 Declaration of competing interest 10 Acknowledgment 10 Appendix A. Supplementary data 10 References 10

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UND

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nonfiction