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Linkages Make a Difference in the Photoluminescence of Covalent Organic Frameworks by Yue Wang; Yuan‐Zhe Cheng; Ke‐Ming Wu; Dong‐Hui Yang; Xin‐Feng Liu; Xuesong Ding; Bao‐Hang Han is a Chemistry article available to read on EtoBox.
What is Linkages Make a Difference in the Photoluminescence of Covalent Organic Frameworks about?
## Abstract Covalent organic frameworks (COFs) with structural designability and tunability of photophysical properties enable them to be a promising class of organic luminescent materials by incorporating well‐designed fluorescent units directly into the periodic skeletons. The photophysical properties of COFs are mainly affected by the structural features, which determine the conjugation degree, charge delocalization ability, and exciton dynamics of COFs. To understand the relationship between COF structures and their photophysical properties, two COFs with the same pyrene chromophore units but different linkages (imine or vinylene) were designed and synthesized. Interestingly, different linkages endow COFs with huge differences in solid‐state photoluminescence quantum yield (PLQY) for imine‐ and vinylene‐linked pyrene‐based COFs, which possess PLQY values of 0.34 % and 15.43 %, respectively. The femtosecond‐transient absorption spectra and time‐dependent density functional theory reveal the different charge‐transfer pathways in imine‐ and vinylene‐linked COFs, which influence the exciton relaxation way and fluorescence intensity. In addition, an effective white‐light device was
Who reads Linkages Make a Difference in the Photoluminescence of Covalent Organic Frameworks?
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- Author
- Yue Wang; Yuan‐Zhe Cheng; Ke‐Ming Wu; Dong‐Hui Yang; Xin‐Feng Liu; Xuesong Ding; Bao‐Hang Han
- Publisher
- Wiley
- Published
- 2023
- Language
- EN
- Field
- Chemistry (Physical Sciences)