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Can I read Anthraquinon-2-ylethyl-1′,2′-diol (Aqe-diol) as a new photolabile protecting group for aldehydes and ketones on EtoBox?
Anthraquinon-2-ylethyl-1′,2′-diol (Aqe-diol) as a new photolabile protecting group for aldehydes and ketones by Jing-yu Yu; Wen-Jian Tang; Hong-Bo Wang; Qin-Hua Song is a Materials Science article available to read on EtoBox.
What is Anthraquinon-2-ylethyl-1′,2′-diol (Aqe-diol) as a new photolabile protecting group for aldehydes and ketones about?
A new photolabile protecting group for aldehydes and ketones, 2-(1,2-dihydroxyethyl) anthraquinone (Aqe-diol) and four caged compounds have been prepared and their photochemistry investigated. Upon 350 nm light irradiation, the caged compounds 2a-d in CH 3 CN-H 2 O solution can efficiently release the carbonyl compounds (conversion rate 60-90%), and their uncaging quantum efficiencies were measured, ranging from 0.03 to 0.09. On the basis of HPLC analysis and quenching experiments, a mechanism of the uncaging reaction was suggested.
Who reads Anthraquinon-2-ylethyl-1′,2′-diol (Aqe-diol) as a new photolabile protecting group for aldehydes and ketones?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Jing-yu Yu; Wen-Jian Tang; Hong-Bo Wang; Qin-Hua Song
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 1010-6030)
- Published
- 2007
- Language
- EN
- Field
- Materials Science (Physical Sciences)