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Electrochemical Radical Silyl‐Oxygenation of Activated Alkenes by Jie Ke; Wentan Liu; Xujiang Zhu; Xingfa Tan; Chuan He is a Chemistry article available to read on EtoBox.

What is Electrochemical Radical Silyl‐Oxygenation of Activated Alkenes about?

## Abstract An efficient electrochemical radical silyl‐oxygenation of electron‐deficient alkenes is demonstrated, which gives access to a variety of new highly functionalized silicon‐containing molecules, including β‐silyl‐cyanohydrin derivatives in good yields with excellent chemo‐ and regio‐selectivity. This electrochemical radical silylation process conducts under mild conditions without the use of transition metal catalyst or chemical oxidant and exhibits a wide scope of substrate silanes with high functional‐group tolerance. The ability to access silyl radicals using electrochemical Si−H activation offers new perspectives for the synthesis of valuable organosilicon compounds in a sustainable and green manner.

Who reads Electrochemical Radical Silyl‐Oxygenation of Activated Alkenes?

Author

Jie Ke; Wentan Liu; Xujiang Zhu; Xingfa Tan; Chuan He

Publisher

Wiley

Published

2021

Language

EN

Field

Chemistry (Physical Sciences)