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Synthesis of Functional π-Conjugated Polymers from Aromatic Acetylenes by Toshiki Aoki; Takashi Kaneko; Masahiro Teraguchi is a Materials Science article available to read on EtoBox.
What is Synthesis of Functional π-Conjugated Polymers from Aromatic Acetylenes about?
Because of their unique structures and properties, p-conjugated polymers have attracted the attention of scientists and engineers. The authors have studied the synthesis of two kinds of p-conjugated poly(aromatic acetylene)s, i.e. poly(arylacetylene)s and poly(aryleneethynylene)s with the aim of obtaining new polymers having novel functions or higher performances. This review mainly concerns the authors' results, as follows: first, we describe the synthesis and properties of achiral poly(arylacetylene)s, containing trimethylsilyl groups, oligodimethylsiloxanyl groups, dendritic groups, and glavinoxyl groups, for application as oxygen permselective membrane materials. Their self-membrane-forming abilities and high oxygen permeabilities are presented. Second, the synthesis by asymmetric-induced polymerization of chiral poly(arylacetylene)s having both a main-chain chirality and chiral pendant groups and their application as optical resolution membranes are described. Third, two new synthetic methods for preparing chiral helical poly(phenylacetylene)s without the coexistence of any other chiral moieties are presented. One is helix-senseselective addition polymerization and the other i
Who reads Synthesis of Functional π-Conjugated Polymers from Aromatic Acetylenes?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Toshiki Aoki; Takashi Kaneko; Masahiro Teraguchi
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0032-3861)
- Published
- 2006
- Language
- EN
- Field
- Materials Science (Physical Sciences)
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