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Lindemann Mechanism in Unimolecular Reactions by jayven minguillan is a document available to read on EtoBox.
What is Lindemann Mechanism in Unimolecular Reactions about?
The document summarizes the Lindemann mechanism for unimolecular reactions in gases. It describes how the mechanism predicts second-order kinetics at low pressures and first-order kinetics at high pressures. However, the theory has two problems: (1) the calculated rate constant k1 exceeds the collision theory limit, and (2) plots of k-1 vs p-1 deviate from linearity at low pressures, contrary to the theory
- Author
- jayven minguillan
- Language
- EN