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Can I read Single Electron-transfer as Rate-determining Step in an Aliphatic Nucleophilic Substitution on EtoBox?
Single Electron-transfer as Rate-determining Step in an Aliphatic Nucleophilic Substitution by Torben Lund; Henning Lund is a Chemistry article available to read on EtoBox.
What is Single Electron-transfer as Rate-determining Step in an Aliphatic Nucleophilic Substitution about?
The rate of the reaction between the anion of 1,4-dihydro-4-methoxycarbonyl-l-methylpyridine (1-j and sterically hindered alkyl halides,and between the perylene dianion (Pe'-) and t-butyl chloride and see-butyl bromide has been measured by electrochemical techniques. The rate was found to be close to the rate of single electron-transfer (SET) from anion radicals (A') with the same standard potential as Y/l-, resp. Pe;/Pe'to the corresponding alkyl hali- des. The kinetic results strongly suggest that a SET mechanism is the rate-determining step in these nucleophilic substitutions.
Who reads Single Electron-transfer as Rate-determining Step in an Aliphatic Nucleophilic Substitution?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Torben Lund; Henning Lund
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 1986
- Language
- EN
- Field
- Chemistry (Physical Sciences)