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ChemInform Abstract: ASYMMETRIC SYNTHESES VIA HETEROCYCLIC INTERMEDIATES. IV. ASYMMETRIC SYNTHESIS S OF α-METHYLPHENYLALANINE AND ITS ANALOGS BY ALKYLATION OF 1-CHIRAL SUBSTITUTED 4-METHYL-2-IMIDAZOLIN-5-ONE by SCHOELLKOPF, U.; HAUSBERG, H.-H.; SEGAL, M.; REITER, U.; HOPPE, I.; SAENGER, W.; LINDNER, K. is a Chemistry article available to read on EtoBox.
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## Abstract Metallierung des aus der chiralen Vorstufe (VI) zugänglichen Isocyanids (I) unter nachfolgender Cyclisierung führt zum anionisierten Imidazolon (III), das mit Benzyl‐ bzw. Heterobenzylhalogeniden (II) mit weit über 95proz. asymm. Induktion (d. e. = diastereomeric excess) zu den (S,S)‐konfigurierten Derivaten (IV) reagiert.
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- Author
- SCHOELLKOPF, U.; HAUSBERG, H.-H.; SEGAL, M.; REITER, U.; HOPPE, I.; SAENGER, W.; LINDNER, K.
- Publisher
- Wiley (John Wiley & Sons); Wiley (ISSN 0009-2975)
- Published
- 1981
- Language
- EN
- Field
- Chemistry (Physical Sciences)