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Diverse Cooperative Reactivity at a Square Planar Aluminium Complex and Catalytic Reduction of CO 2 by Chloe L. Shaves; Nery Villegas‐Escobar; Ewan R. Clark; Ian M. Riddlestone is a Chemistry article available to read on EtoBox.

What is Diverse Cooperative Reactivity at a Square Planar Aluminium Complex and Catalytic Reduction of CO 2 about?

The use of a sterically demanding pincer ligand to prepare an unusual square planar aluminium complex is reported. Due to the constrained geometry imposed by the ligand scaffold, this four-coordinate aluminium centre remains Lewis acidic and reacts via differing metal-ligand cooperative pathways for activating ketones and CO 2 . It is also a rare example of a single-component aluminium system for the catalytic reduction of CO 2 to a methanol equivalent at room temperature.

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Author

Chloe L. Shaves; Nery Villegas‐Escobar; Ewan R. Clark; Ian M. Riddlestone

Publisher

Wiley

Published

2023

Language

EN

Field

Chemistry (Physical Sciences)