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Acetonitrile(6,6′-dimethyl-2,2′-dipyridyl)silver(I) trifluoromethanesulfonate by Klausmeyer, Kevin K. ;Hung-Low, Fernando ;Renz, Amanda is a Chemistry article available to read on EtoBox.

What is Acetonitrile(6,6′-dimethyl-2,2′-dipyridyl)silver(I) trifluoromethanesulfonate about?

In the title compound, [Ag(CH 3 CN)(C 12 H 12 N 2 )]CF 3 SO 3 , the Ag atom is three-coordinated by one 6,6 0 -dimethyl-2,2 0dipyridyl ligand and one acetonitrile molecule, with trifluoromethanesulfonate acting as a noncoordinating counter-ion. The two pyridyl rings of the bipyridine ligand are nearly coplanar with a twist angle of 5.35 (5) between the two mean planes. The commonly seen -stacking interaction between the aromatic rings in bipyridine complexes, which reinforces further silver-silver interactions, is not observed in the crystal structure of the sterically hindered compound.

Who reads Acetonitrile(6,6′-dimethyl-2,2′-dipyridyl)silver(I) trifluoromethanesulfonate?

Author

Klausmeyer, Kevin K. ;Hung-Low, Fernando ;Renz, Amanda

Publisher

International Union of Crystallography; Chester UK: International Union of Crystallography, 2001-2014.; [S.l.]: Wiley-Blackwell; [Chester]: 2008-; International Union of Crystallography (IUCr) (ISSN 1600-5368)

Published

2007

Language

ZU

Field

Chemistry (Physical Sciences)