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This document presents a new derivation of the Kirkwood-Frohlich equation, which relates the dielectric constant of a liquid to its molecular properties. The derivation shows that within the limitations of molecules characterized by a permanent dipole moment and polarizability, the Kirkwood-Frohlich equation holds rigorously for a cubic lattice. For liquids, the approximation is made that translational fluctuations can be neglected and positions are independent of orientations. The derivation calculates the

Author

maxxagain

Language

EN