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This document discusses the first enantioselective [4 + 3] cycloaddition of ortho-hydroxyphenyl substituted para-quinone methides with isatin-derived enals, utilizing N-heterocyclic carbene (NHC) catalysis. The methodology allows for the synthesis of biologically significant e-lactones with high yields and enantioselectivities, expanding the scope of cycloaddition reactions in organic chemistry. The study highlights the potential for developing new synthetic strategies for complex cyclic structures importan

Author
MohitChahal
Language
EN