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Mesocrystal morphology regulation by “alkali metals ion switch”: Re-examining zeolite nonclassical crystallization in seed-induced process 1 1 Introduction 2 2 Materials and methods 2 2.1 Materials 2 2.2 Synthesis of samples 3 2.3 Characterization 4 3 Results and discussion 4 3.1 Morphology and mesocrystal structure of ZSM-5 obtained via the “Na+-K+ ion switch” strategy 4 3.2 Multiple growth curve analysis of MZ5-K and MZ5-Na 5 3.3 Deep excavating the formation pathway of MZ5-K/Na by tracking the crystallization process 5 3.4 Reverse analysis by the dissolution experiment. 8 3.5 Uncover the nonclassical crystallization mechanism and reveal how the “ion switch” works 9 3.6 Weighing the applicability and flexibility of the “ion switch” strategy 9 4 Conclusion 10 CRediT authorship contribution statement 10 Declaration of Competing Interest 10 Acknowledgments 10 Appendix A Supplementary data 10 References 10
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