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Concerning the origin of 19F19F NMR COSY and NOESY connections in the spectra of perfluorooctanoic acid, RF-palmitic acid-F13 and diethyl perfluorosuberate by Gerald W. Buchanan; Elena Munteanu; Brian A. Dawson; Derek Hodgson is a Chemistry article available to read on EtoBox.
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## Abstract A combination of ^19^F nuclear Overhauser effects (NOE) and molecular mechanics calculations are presented for delineating the spatial origin of the well‐known four‐bond ^19^F^19^F COSY connections which are generally observed in the ^19^F NMR spectra of compounds containing perfluorinated chains. Perfluorooctanoic acid (PFOA), R~F~‐palmitic acid‐F~13~ and diethyl perfluorosuberate were used as test cases. Spin–lattice relaxation times (__T__~1~) are included and NOESY correlations through three and four bonds occur. Copyright © 2005 John Wiley & Sons, Ltd.
Who reads Concerning the origin of 19F19F NMR COSY and NOESY connections in the spectra of perfluorooctanoic acid, RF-palmitic acid-F13 and diethyl perfluorosuberate?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Gerald W. Buchanan; Elena Munteanu; Brian A. Dawson; Derek Hodgson
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; John Wiley and Sons Ltd; Wiley (ISSN 0749-1581)
- Published
- 2005
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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