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Synthesis of tetramethyldisilane-bridged bis(1-indenyl) tetracarbonyl di-iron: A novel thermal rearrangement reaction between the Si-Si and Fe-Fe bonds by Bai-Quan Wang; Shan-Sheng Xu; Xiu-Thong Zhou is a Chemistry article available to read on EtoBox.

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The title complex (Me2SiSiMe2)[(lqS-l-indenyl)Fe(CO)]2(iz-CO)2 (1) was prepared by the reaction of 1,2-bis(l-indenyl)telramethyldisilane and Fe(CO) 5 in refluxing hetmme. Its thermal rearrangement product [Me2Si(~qS-l-indenyl)Fe(CO)2]2 (2) was also obtained from the reaction. 1 in refluxing xylene can be readily converted into 2. The crystal structures of the cis isomer le and the tram isomer 2t were determined by X-ray diffraction.

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Author

Bai-Quan Wang; Shan-Sheng Xu; Xiu-Thong Zhou

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1997

Language

EN

Field

Chemistry (Physical Sciences)