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Solvent‐Free and TMEDA‐Solvated Mixed Alkali Metal‐Magnesium Tris‐diisopropylamides by Eva Hevia; Fiona R. Kenley; Alan R. Kennedy; Robert E. Mulvey; René B. Rowlings is a Chemistry article available to read on EtoBox.

What is Solvent‐Free and TMEDA‐Solvated Mixed Alkali Metal‐Magnesium Tris‐diisopropylamides about?

## Abstract A trio of heterobimetallic tris‐diisopropylamides, the solvent‐free potassium‐magnesium amide [{KMg(N__i__Pr~2~)~3~}~∞~], its TMEDA solvate [KMg(N__i__Pr~2~)~3~·TMEDA] and the sodium congener [NaMg(N__i__Pr~2~)~3~·TMEDA] has been synthesised by mixing the appropriate metal alkyl reagents with three molar equivalents of diisopropylamine in a hydrocarbon medium, to which, in the last two cases, TMEDA is added. All three amides have been successfully crystallographically characterised by X‐ray diffraction studies. Representing the first pure __s__‐block mixed‐metal diisopropylamide free of solvent molecules or other stabilising anionic co‐ligands, the first compound adopts an infinite spiral chain of ···K‐(μ‐N)~2~‐Mg‐N··· links, the metal‐N framework of which is supported by agostic K···C intra‐dinuclear and inter‐dinuclear contacts. The dinuclear tris‐amido motif is maintained in both TMEDA complexes, the metal‐N cores of which are essentially isostructural, but the presence of the chelating diamine blocks the propagating terminal site on the alkali metal and so gives rise to discrete molecular structures. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003

Who reads Solvent‐Free and TMEDA‐Solvated Mixed Alkali Metal‐Magnesium Tris‐diisopropylamides?

Author

Eva Hevia; Fiona R. Kenley; Alan R. Kennedy; Robert E. Mulvey; René B. Rowlings

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1434-1948)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)