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Can I read Propagation Kinetics of Free-radical Polymerizations in Ionic Liquids on EtoBox?
Propagation Kinetics of Free-radical Polymerizations in Ionic Liquids by Inga Woecht; Gudrun Schmidt-Naake; Sabine Beuermann; Michael Buback; Nuria García is a Materials Science article available to read on EtoBox.
What is Propagation Kinetics of Free-radical Polymerizations in Ionic Liquids about?
## Abstract Propagation rate coefficients, __k__~p~, of methyl methacrylate (MMA) and glycidyl methacrylate (GMA) homopolymerizations were measured at ambient pressure in four ionic liquids (ILs): 1‐ethyl‐3‐methylimidazolium ([emim]) ethyl sulfate and [emim] hexyl sulfate as well as butyl‐3‐methylimidazolium ([bmim]) hexafluorophosphate and [bmim] tetrafluoroborate via the pulsed‐laser polymerization size‐exclusion chromatography technique. In passing from bulk polymerization at 40 °C polymerization in IL solution containing 20 vol % monomer, __k__~p~ is enhanced by up to a factor of 4 with MMA and by a factor of 2 with GMA. This enhancement of __k__~p~ primarily results from a lowering of activation energy upon partial replacement of monomer by ionic liquid species. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 1460–1469, 2008
Who reads Propagation Kinetics of Free-radical Polymerizations in Ionic Liquids?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Inga Woecht; Gudrun Schmidt-Naake; Sabine Beuermann; Michael Buback; Nuria García
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0887-624X)
- Published
- 2007
- Language
- EN
- Field
- Materials Science (Physical Sciences)