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Kinetic Evidence for the Mechanistic Difference in the Aqueous Polymerization of Acrylonitrile by Hariharan, S. S. ;Maruthamuthu, Meenakshi is a Chemistry article available to read on EtoBox.

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## Abstract Kinetic evidence indicated two different mechanistic pathways in the polymerization of acrylonitrile initiated by peroxodiphosphate‐vanadyl ion redox system in aqueous solution depending upon the concentration of the reducing metal ion employed. The mechanistic difference lies in the termination reaction, exclusively mutual termination occurring in the concentration range [VO^2+^]=2,5·10^−3^ to 5·10^−3^ mol·dm^−3^ and exclusively linear termination taking place in the concentration range [VO^2+^] =10^−2^ to 25·10^−3^ mol·dm^−3^.

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Author

Hariharan, S. S. ;Maruthamuthu, Meenakshi

Publisher

Wiley (John Wiley & Sons); Wiley (ISSN 0025-116X)

Published

1979

Language

EN

Field

Chemistry (Physical Sciences)