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Can I read Highly Robust and Efficient Blechert-Type Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Olefin Metathesis on EtoBox?
Highly Robust and Efficient Blechert-Type Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Olefin Metathesis by Antonio Del Vecchio; Jakub Talcik; Sophie Colombel-Rouen; Jan Lorkowski; Melinda R. Serrato; Thierry Roisnel; Nicolas Vanthuyne; Guy Bertrand; Rodolphe Jazzar; Marc Mauduit is a Chemistry article available to read on EtoBox.
What is Highly Robust and Efficient Blechert-Type Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Olefin Metathesis about?
New Blechert-type ruthenium complexes containing cyclic(alkyl)(amino)carbene (CAAC) ligands are reported. These catalysts demonstrate remarkable thermal stability in solution and excellent catalytic performances at low catalytic loading (up to 0.005 mol %) in ring-closing metathesis (RCM), macro-RCM, ring-closing enyne metathesis (RCEYM), cross-metathesis (CM), ethenolysis and ring-opening cross metathesis (ROCM). Moreover, up to 95% enantiomeric excess (ee) was obtained in asymmetric ring-opening cross metathesis (AROCM) and 57% ee was obtained in asymmetric cross-metathesis (ACM).
Who reads Highly Robust and Efficient Blechert-Type Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Olefin Metathesis?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Antonio Del Vecchio; Jakub Talcik; Sophie Colombel-Rouen; Jan Lorkowski; Melinda R. Serrato; Thierry Roisnel; Nicolas Vanthuyne; Guy Bertrand; Rodolphe Jazzar; Marc Mauduit
- Publisher
- American Chemical Society (ACS)
- Published
- 2023
- Language
- EN
- Field
- Chemistry (Physical Sciences)