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The document discusses the growth of needle-shaped crystals of K- or Rb-containing α-MnO2 through molten salt electrolysis, achieving sizes up to 3 mm. The study highlights the successful synthesis of these crystals in air or oxygen using platinum electrodes, while noting that no α-MnO2 was formed with Cs, leading to different compounds. Experimental results indicate that the hollandite-type MxMnO2 was predominantly obtained, and the formation mechanisms and conditions for the various phases are explored.

Author

ARIANA DE CAMPOS

Language

EN