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Can I read Reactions of Aniline in Acetic Acid Solutions Containing Cyanuric Chloride and Hydrogen Chloride Acceptors on EtoBox?
Reactions of Aniline in Acetic Acid Solutions Containing Cyanuric Chloride and Hydrogen Chloride Acceptors by Kirill A Kolmakov is a Chemistry article available to read on EtoBox.
What is Reactions of Aniline in Acetic Acid Solutions Containing Cyanuric Chloride and Hydrogen Chloride Acceptors about?
Two reaction pathways in acetic acid solution containing cyanuric chloride, aniline, and some hydrogen chloride acceptors (triethylamine, sodium acetate, pyridine) were studied. Both aryl amination and acylation can be performed with high yields under proper reaction conditions. Contrary to the only known literature report on the reactions between carbonic acids and cyanuric chloride in the presence of a hydrogen chloride acceptor (triethylamine), it was established that acid chlorides are not formed. A scheme involving the replacement of chlorine atoms by acetate ion in the initial stage was proposed for the acylation of aniline promoted by cyanuric chloride.Key words: acetic acid, acylation, aniline, cyanuric chloride, aryl amination.
Who reads Reactions of Aniline in Acetic Acid Solutions Containing Cyanuric Chloride and Hydrogen Chloride Acceptors?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Kirill A Kolmakov
- Publisher
- Canadian Science Publishing
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)