Can I read The thermal metathesis reaction between SiSi and FeFe bonds of [Me2Si-η5-C5H3(SiMe2SiMe3)(CO)Fe(CO)2Fe(CO)-η5-C5H3(SiMe2SiMe3)SiMe2]. Regiospecific cleavage of the SiSi bond in the cyclic structure on EtoBox?

The thermal metathesis reaction between SiSi and FeFe bonds of [Me2Si-η5-C5H3(SiMe2SiMe3)(CO)Fe(CO)2Fe(CO)-η5-C5H3(SiMe2SiMe3)SiMe2]. Regiospecific cleavage of the SiSi bond in the cyclic structure by Huailin Sun; Xuebin Huang; Zhong Hu; Zhensheng Zhang; Xuebing Leng; Linhong Weng is a Chemistry article available to read on EtoBox.

What is The thermal metathesis reaction between SiSi and FeFe bonds of [Me2Si-η5-C5H3(SiMe2SiMe3)(CO)Fe(CO)2Fe(CO)-η5-C5H3(SiMe2SiMe3)SiMe2]. Regiospecific cleavage of the SiSi bond in the cyclic structure about?

4) as a mixture of diastereomers. The rac and meso isomers of 4 (i.e. trans -4 and cis -4) may be separated completely by column chromatography and undergo the thermal metathesis reaction between their Si Ã/Si and Fe Ã/Fe bonds to give the rac and meso isomers of [Me 2 Si-h 5 -C 5 H 3 (SiMe 2 SiMe 3 )Fe(CO) 2 SiMe 2 -h 5 -C 5 H 3 (SiMe 2 SiMe 3 )Fe(CO) 2 ] (5) (i.e. cis -5 and trans -5) in a stereospecific fashion. It is noteworthy that the metathesis reactions of trans -4 and cis -4 involve regiospecific cleavage of the Si Ã/Si bond inside the cyclic structure with retention of those outside. Crystal and molecular structures of cis -4 and trans -5 have been determined by X-ray diffraction methods.

Who reads The thermal metathesis reaction between SiSi and FeFe bonds of [Me2Si-η5-C5H3(SiMe2SiMe3)(CO)Fe(CO)2Fe(CO)-η5-C5H3(SiMe2SiMe3)SiMe2]. Regiospecific cleavage of the SiSi bond in the cyclic structure?

Author

Huailin Sun; Xuebin Huang; Zhong Hu; Zhensheng Zhang; Xuebing Leng; Linhong Weng

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)