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Can I read Kinetic behaviour of benzoylperoxy radicals in the presence of NO and NO2 on EtoBox?
Kinetic behaviour of benzoylperoxy radicals in the presence of NO and NO2 by F. Kirchner; F. Zabel; K.H. Becker is a Physics and Astronomy article available to read on EtoBox.
What is Kinetic behaviour of benzoylperoxy radicals in the presence of NO and NO2 about?
Benzoyl peroxynitrate (C6HSC(0)02N02) was prepared in situ in a 420 B photoreactor by continuous photolysis of Cl\*/ CsH5CH0/02/N02/N2 mixtures. From the loss of benzoyl peroxynitrate in the presence of different amounts of NO and NOz, rate constants of the reaction CsH5C(0)02N02 (+M) -+CsHsC(0)OZ+N02 ( +M) (-2) and rate constant ratios k,/k, of the reactions CsHSC(0)02+N02 ( +M)+C6H5C(0)OZN02 (+M) (2) and C6HSC(0)02+NO-+products (1) weredetermined. The temperature and pressure dependence of k\_z can be described by the expressions developed by Troe and co-workers with the fo~owingparameters:~/[Nz]=3.4x10-\*exp(-92.6klmo1~'/RT)cm"mo1ecule~'s~',k,=1.1~10"exp(-117.0kTmo1-'/ RT) s-', F,=O.25. The ratio k2/kI is 0.63 f0.07 in the temperature range 310-322 K and in 1000 mbar N2.
Who reads Kinetic behaviour of benzoylperoxy radicals in the presence of NO and NO2?
It is typically read by researchers, students, and practitioners in Physics and Astronomy.
- Author
- F. Kirchner; F. Zabel; K.H. Becker
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)
- Published
- 1992
- Language
- EN
- Field
- Physics and Astronomy (Physical Sciences)