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Pericyclic reactions are concerted reactions that proceed through cyclic transition states. There are several types of pericyclic reactions including cycloadditions, electrocyclic reactions, and sigmatropic shifts. Cycloadditions are classified as (4+2) or (2+2) depending on the number of pi electrons involved. Electrocyclic reactions involve the formation or breaking of a ring through the generation or loss of a sigma bond. The mechanism and products of pericyclic reactions can be understood and predicted

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fimiwm

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EN