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Dealkenylative Functionalizations: Conversion of Alkene C(sp3)–C(sp2) Bonds into C(sp3)–X Bonds via Redox-Based Radical Processes by Ohyun Kwon; Brady W. Dehnert; Jeremy H. Dworkin is a Chemistry article available to read on EtoBox.

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Abstract This review highlights the history and recent advances in dealkenylative functionalization. Through this deconstructive strategy, radical functionalizations occur under mild, robust conditions. The reactions described proceed with high efficiency, good stereoselectivity, tolerate many functional groups, and are completed within a matter of minutes. By cleaving the C(sp3)–C(sp2) bond of terpenes and terpenoid-derived precursors, rapid diversification of natural products is possible. 1 Introduction 2 Mechanism 3 History 4 Motivation to Pursue Dealkenylation 5 Dealkenylation in the Present 6 Conclusion

Who reads Dealkenylative Functionalizations: Conversion of Alkene C(sp3)–C(sp2) Bonds into C(sp3)–X Bonds via Redox-Based Radical Processes?

Author

Ohyun Kwon; Brady W. Dehnert; Jeremy H. Dworkin

Publisher

Georg Thieme Verlag KG

Published

2023

Language

EN

Field

Chemistry (Physical Sciences)