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Low-temperature reactions of some atomic ions with molecules of large quadrupole moment: C6F6 and c-C6H12 by C. Rebrion; J.B. Marquette; B.R. Rowe; N.G. Adams; D. Smith is a Physics and Astronomy article available to read on EtoBox.

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Reactions of He+, C+ and N+ ions with C,F, and c-C~H,~ were examined at 27, 68 and 297 K using both CRESU and SIFT techniques. Within the experimental uncertainties, all of the rate coeffkients are found to be temperature-independent in this range. The results are discussed in relation to the most recent theoretical models describing the influence of the quadrupole moment on the temperature dependence of ion-molecule reaction rate coefficients.

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Author

C. Rebrion; J.B. Marquette; B.R. Rowe; N.G. Adams; D. Smith

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

1987

Language

EN

Field

Physics and Astronomy (Physical Sciences)