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The document discusses the Maxwell relation ∂S/∂p|_T = - ∂V/∂T|_p and questions its validity. It analyzes a modified photon gas system with internal energy U = K.S^β/V^(1-β) and shows the derivatives in the Maxwell relation do not exist, making it a null equation. More generally, for systems described by an internal energy function U(X1,...Xn) of extensive variables, the Maxwell-transformed energy potential U[x1,...xn] is always zero and the apparent Maxwell relations reduce to 0=0. The document concludes t
- Author
- api-322826450
- Language
- EN