Can I read Synthesis, X‐Ray Structure and Complexation Behavior of the New Tripodal Phosphane Ligand cis, cis ‐1,3,5‐Tris[(diphenylphosphanyl)methyl]1‐1,3,5‐trimethylcyclohexane (tdppmtmcy). Crystal Structure of Ir(tdppmtmcy)(CO)Cl on EtoBox?

Synthesis, X‐Ray Structure and Complexation Behavior of the New Tripodal Phosphane Ligand cis, cis ‐1,3,5‐Tris[(diphenylphosphanyl)methyl]1‐1,3,5‐trimethylcyclohexane (tdppmtmcy). Crystal Structure of Ir(tdppmtmcy)(CO)Cl by Hermann A. Mayer; Riad Fawzi; Manfred Steimann is a Chemistry article available to read on EtoBox.

What is Synthesis, X‐Ray Structure and Complexation Behavior of the New Tripodal Phosphane Ligand cis, cis ‐1,3,5‐Tris[(diphenylphosphanyl)methyl]1‐1,3,5‐trimethylcyclohexane (tdppmtmcy). Crystal Structure of Ir(tdppmtmcy)(CO)Cl about?

The introduction of three methyl groups into the ips0 positions analysis) in the solid state. Treatment of 5 with Ir(PPh&(CO)Cl of the cyclohexane ring in cis,cis-l,3,5-tris[(diphenylphos-gives 6 where the two PPh3 groups are replaced by two (diphanyl)methyl]cyclohexane (tdppmcy) (1) leads to the new phenylphosphany1)methyl groups of the ligand 5. In addition, tripodal phosphane ligand cis,cis-1,3,5-tris[(diphenylphos-an intramolecular C-H metalation takes place resulting in the phanyl)methyl]-l,3,5-trimethylcyclohexane (tdppmtmcy) (5). oxidative addition of a ring methylene C-H bond to the metal. The dynamic behavior is studied by variable-temperature NMR spectroscopy and compared with the structure (X-ray The X-ray structure of 6 is determined.

Who reads Synthesis, X‐Ray Structure and Complexation Behavior of the New Tripodal Phosphane Ligand cis, cis ‐1,3,5‐Tris[(diphenylphosphanyl)methyl]1‐1,3,5‐trimethylcyclohexane (tdppmtmcy). Crystal Structure of Ir(tdppmtmcy)(CO)Cl?

Author

Hermann A. Mayer; Riad Fawzi; Manfred Steimann

Publisher

Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 0009-2940)

Published

1993

Language

EN

Field

Chemistry (Physical Sciences)