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Hydrothermal Synthesis and Crystal Structure of a Meso-Helical Chain Based on Lindqvist Polyoxometalates by Chun-Jing Zhang; Rui Fang; Yan Yu; Hai-Jun Pang; Hui-Yuan Ma; De-Sheng Cui; Dong-Ping Li is a Chemistry article available to read on EtoBox.
What is Hydrothermal Synthesis and Crystal Structure of a Meso-Helical Chain Based on Lindqvist Polyoxometalates about?
A new Lindqvist polyoxometalate-based hybrid compound with a helical chain structure, [Cu(bipy)~2~][W~6~O~19~] (1), (bipy = 2;20`-bipyridine), has been hydrothermally synthesized and characterized by elemental analysis, infrared spectroscopy, thermogravimetry, and single-crystal X-ray diffraction. The compound crystallizes in the space group C2/c of the monoclinic system. In 1, the [W~6~O~19~]^2-^ anions are connected alternately with [Cu(bipy)~2~]^2+^ subunits to form a meso-helical chain. To our knowledge, this structure represents the first example of a helical chain structure consisting of the hexatungstate anion [W~6~O~19~]^2-^. The electrochemical properties of the title compound have been studied.
Who reads Hydrothermal Synthesis and Crystal Structure of a Meso-Helical Chain Based on Lindqvist Polyoxometalates?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Chun-Jing Zhang; Rui Fang; Yan Yu; Hai-Jun Pang; Hui-Yuan Ma; De-Sheng Cui; Dong-Ping Li
- Publisher
- Walter de Gruyter GmbH
- Published
- 2013
- Language
- EN
- Field
- Chemistry (Physical Sciences)