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1,1′-Bis(diphenylphosphino)cobaltocenium tetrafluoridoborate by Hou, Jian-Guo ;Zhang, Pu ;Ye, Chen ;Yu, Tie-Gang is a Chemistry article available to read on EtoBox.

What is 1,1′-Bis(diphenylphosphino)cobaltocenium tetrafluoridoborate about?

The title compound, [Co(C~17~H~14~P)~2~]BF~4~, was obtained by the anion exchange of 1,1′-bis(diphenylphosphino)cobaltocenium chloride with sodium tetrafluoroborate. Both the cation and anion lie on crystallographic twofold axes which run through the Co^III^ ion, and both the B atom and one F atom of the anion, respectively. Three of the F atoms of the BF~4~ ^−^ anion are disordered equally over two sites. The two diphenylphosphine ligands are __trans__ to each other with respect to the Co^III^ ion. The crystal structure contains weak C—H...F interactions.

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Author

Hou, Jian-Guo ;Zhang, Pu ;Ye, Chen ;Yu, Tie-Gang

Publisher

International Union of Crystallography; Chester UK: International Union of Crystallography, 2001-2014.; [S.l.]: Wiley-Blackwell; [Chester]: 2008-; International Union of Crystallography (IUCr) (ISSN 1600-5368)

Published

2007

Language

EN

Field

Chemistry (Physical Sciences)