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Synthesis, Characterisation and Electronic Properties of Naphthalene Bridged Disilanes by Kristel M. Rabanzo-Castillo; Muhammad Hanif; Tilo Söhnel; Erin M. Leitao is a Chemistry article available to read on EtoBox.

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Synthesis of naphthalene bridged disilanes 2 (R = Me, Ph) was performed via catalytic dehydrocoupling. Using RhCl(PPh) as a catalyst, an intramolecular Si-Si bond was readily formed from the corresponding disilyl precursors 1 (R = Me, Ph). For catalytic reactions using (CF)B(OH), bridged siloxanes (3 and 3) were observed. Attempts to install the 1,8-naphthalene bridge directly onto a disilane resulted in an unusual product (4), containing two silicon centres bridged through one naphthyl group, and another naphthyl group attached to a single Si centre. In order for this product to form, both a Si to Si hydrogen shift rearrangement as well as Si-Si bond cleavage occurred. The effects of phenyl and methyl substitutions on the structure and electronic properties of the synthesised compounds was investigated by single crystal X-ray diffraction, as well as IR and multinuclear NMR spectroscopic analysis. In addition, theoretical UV-Vis absorption maxima were evaluated using density functional theory (TD-SCF) on a B3LYP/6-31(++)G\*\* level of theory and compared with experimental UV-Vis spectroscopic data.

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Author

Kristel M. Rabanzo-Castillo; Muhammad Hanif; Tilo Söhnel; Erin M. Leitao

Published

2019

Language

EN

Field

Chemistry (Physical Sciences)