Can I read Ethyl 2-{[2-(3-nitro­phenyl)-5-phenyl-1H-imidazol-4-yl]­sulfanyl}acetate: synthesis via a microwave-mediated combinatorial chemistry approach on EtoBox?

Ethyl 2-{[2-(3-nitro­phenyl)-5-phenyl-1H-imidazol-4-yl]­sulfanyl}acetate: synthesis via a microwave-mediated combinatorial chemistry approach by John F. Gallagher; Clare M. Coleman; Donal F. O'Shea is a Chemistry article available to read on EtoBox.

What is Ethyl 2-{[2-(3-nitro­phenyl)-5-phenyl-1H-imidazol-4-yl]­sulfanyl}acetate: synthesis via a microwave-mediated combinatorial chemistry approach about?

The orange title compound, C 19 H 17 N 3 O 4 S, can be synthesized either via microwave-mediated combinatorial chemistry strategies or conventional synthetic procedures. The phenyl and meta-nitrophenyl C 6 rings are essentially coplanar with the central imidazolyl ring, with interplanar angles of 0.87 (5) and 0.97 (4) , respectively, resulting in optimum conjugation (SCH 2 moiety included); ! max = 281 nm in CH 3 CN. The principal intermolecular interactions are N imid ÐHÁ Á ÁO nitro and N imid ÐHÁ Á ÁO C [NÁ Á ÁO = 3.058 (2) and 3.432 (3) A Ê , and NÐHÁ Á ÁO = 128 and 153 , respectively]. The closest HÁ Á ÁS distance is an intramolecular CÐHÁ Á ÁS contact, with HÁ Á ÁS = 2.54 A Ê and CÐHÁ Á ÁS = 136 .

Who reads Ethyl 2-{[2-(3-nitro­phenyl)-5-phenyl-1H-imidazol-4-yl]­sulfanyl}acetate: synthesis via a microwave-mediated combinatorial chemistry approach?

Author

John F. Gallagher; Clare M. Coleman; Donal F. O'Shea

Publisher

International Union of Crystallography; Blackwell Publishing Inc.; International Union of Crystallography (IUCr); Wiley (ISSN 0108-2701)

Published

2002

Language

EN

Field

Chemistry (Physical Sciences)