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Flash Point Prediction of Binary Partially and Totally Miscible Alcohol-water Mixtures by Various Equation of States and Experimental Validation by Mahdi Yousefi; Elahe Mansouri; Hossein Jalaei Salmani; Mohammad Reza Moradi; Horng-Jang Liaw; Kazem Lakzian is a Engineering article available to read on EtoBox.
What is Flash Point Prediction of Binary Partially and Totally Miscible Alcohol-water Mixtures by Various Equation of States and Experimental Validation about?
In the present article, the experimental flash points (FPs) of partially miscible and non-ideal mixtures including 3-pentanol þ water, 2-pentanol þ water, and 1-hexanol þ water are reported for the first time. The measured FPs were predicted based on the vapor pressure concept and thermodynamic equilibrium. The cubic-plus-association (CPA) equation of state (EoS) along with the CR-1 combining rule and Elliot combining rule (ECR) were used to investigate the non-ideality of investigated systems. In the following, the same method was used with the Soave-Redlich-Kwong (SRK) and Peng-Robinson (PR) EoSs to evaluate whether simpler EoSs can accurately predict the FPs of non-ideal mixtures. Therefore, in addition to 3-pentanol þ water, 2-pentanol þ water, and 1-hexanol þ water, numerous totally and partially miscible aqueous-organic systems containing 1-pentanol, isobutanol, 2-butanol, 1-butanol, isopropanol, propanol, ethanol, and methanol were studied in terms of FP prediction. The findings indicated that SRK is marginally more effective than PR. Moreover, SRK EoS was almost as effective as the CPA EoS with the CR-1 combining rule. The CPA EoS that used ECR, on the other hand, was far s
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It is typically read by researchers, students, and practitioners in Engineering.
- Author
- Mahdi Yousefi; Elahe Mansouri; Hossein Jalaei Salmani; Mohammad Reza Moradi; Horng-Jang Liaw; Kazem Lakzian
- Publisher
- Informa UK Limited
- Published
- 2023
- Language
- EN
- Field
- Engineering (Physical Sciences)