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Smart Guanyl Thiosemicarbazide Functionalized Dialdehyde Cellulose for Removal of Heavy Metal Ions from Aquatic Solutions: Adsorption Characteristics and Mechanism Study by Magda A. Akl; Abdelrahman S. El-Zeny; Mohamed Ismail; Mohamed Abdalla; Dina Abdelgelil; Aya G. Mostafa is a Environmental Science article available to read on EtoBox.

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## Abstract In recent years, facing the problem of improving environmental quality, cellulose and cellulose-based (nano) composites have received great attention as adsorbents. In this work, we report the modification and functionalization of cellulose by nitrogen- and sulfur-containing moieties through a three-steps process; native cellulose is first oxidized by potassium periodate (KIO~4~) to form dialdehyde cellulose (DAC), which then condenses with aminoguanidine and react with phenyl isothiocyanate to form 4-phenyl guanyl thiosemicarbazide dialdehyde cellulose (DAC@GuTSC). The prepared DAC@GuTSC is characterized by a number of techniques, including Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), elemental analysis (EA), Brunauer–Emmett–Teller (BET) and thermogravimetric analysis (TGA). The prepared DAC@GuTSC adsorbent was used to remove Cu^2+^ Hg^2+^ and Pb^2+^ from aqueous solution and environmental water samples. The influence of various factors on the adsorption efficiency including pH, initial metal concentration, contact time, adsorbent dosage, temperature, and ions interfering with adsorption was investigated. Under optimal adsorption

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It is typically read by researchers, students, and practitioners in Environmental Science.

Author
Magda A. Akl; Abdelrahman S. El-Zeny; Mohamed Ismail; Mohamed Abdalla; Dina Abdelgelil; Aya G. Mostafa
Publisher
Springer Science and Business Media LLC
Published
2023
Language
EN
Field
Environmental Science (Physical Sciences)

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